Property and Structure Characterization of High Molecular Weight Polyacrylonitrile Polymers Initiated by 2,2'-Azobis (2-methyl propionamide) Dihydrochloride Using Aqueous Deposited Polymerization Technique
نویسندگان
چکیده
Powdery high molecular weight polyacrylonitrile (HMW-PAN) polymers were successfully synthesized by aqueous deposited polymerization (ADP) method with 2,2'-azobis (2-methyl propionamide) dihydrochloride (AIBA) as the initiator and itaconic acid (IA) comonomer. The utilization of IA into ADP system was conducive to relax proceeding thermo-oxidation process. Differential scanning calorimeter (DSC) curves obtained PAN copolymers showed doublet peaks character under air atmosphere, attributing exothermic cyclization oxidative reactions during heat-treatment With in reaction system, crystallinity grain sizes decreased. stretching vibration nitrile group (C?N) at 2240cm-1 strongest peak both Fourier transform infrared spectra (FTIR). And bending CH2 stronger FTIR. Amido (NH2), carbonyl (C=O) C-O single bond existed FTIR homopolymer copolymers, indicating occurrence C?N hydrolysis process except carboxyl (COOH) introduced IA.
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ژورنال
عنوان ژورنال: MATEC web of conferences
سال: 2022
ISSN: ['2261-236X', '2274-7214']
DOI: https://doi.org/10.1051/matecconf/202235801028